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Organic Electronics
    Moisture Transport through Ultra-Low Permeation Barriers
    Chemistry and Orientation with NEXAFS Spectroscopy
Nanoimprint Lithography
  Pattern Transfer and Stability
Polymers for Next-Generation Lithography
  Dissolution Fundamentals
  Surface and Bulk Chemistry of Chemically Amplified Photoresists
  NIST-Industry Partnerships
Dimensional Metrology with Small Angle X-ray Scattering
  Sidewall Angle Metrology
  Dimensional Changes during Fabrication
Characterization of Porous Low-k Dielectric Thin Films
 
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Polymers for Next-Generation Lithography

 

Introduction

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  • The enabling technology to fabricate integrated circuits with ever decreasing feature sizes
  • Next-generation photoresists must meet nanometer scale critical dimension (CD) control and line-edge roughness (LER) requirements.
  • Polymers for Next-Generation Lithography   Polymers for Next-Generation Lithography    Polymers for Next-Generation Lithography
     

    Objective

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    Polymers for Next-Generation Lithography
  • Develop and apply high-spatial resolution measurements to enable the development of next-generation photoresists
  • Determine relative contribution of material and interfacial factors in photoresist and anti-reflective coatings formulations on CD control and LER
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    NIST Role

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    Polymers for Next-Generation Lithography
  • New measurements to answer critical questions
  • Fundamental studies with broad technology impact
  • Applicable to next-generation photoresist materials
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    Highlights

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    Highlights
  • Photoacid reaction-diffusion front: nanometer resolution
  • Developer distribution in ultra-thin films
  • Water segregation: Interfacial and confinement dependence
  • Nanometer chemical depth profiling method
  • Antireflective coating / resist interfacial chemistry
  • Developer contributions to line-edge roughness
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    Customers and Impact

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    companies
  • ISMT Proposal “Understanding Materials Causes of Line-Edge Roughness”
  • DARPA Advanced Lithography Program Contract # N66001-00-C-8083
  • Semiconductor Fabtech invited article
  • Industry initiated contact for collaborative work.
  • NIST Office of Microelectronics Programs
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    NIST Contributors

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    Vivek Prabhu*
    Eric Lin
    Wen-li Wu
    Erin Jablonski
    Bryan Vogt
    Christopher Soles
    Ronald Jones
    Tengjiao Hu
    David VanderHart
    Michael Wang
    Dan Fischer
    S. Sambasivan
    Sushil Satija
    NCNR
     

    Collaborators:

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    Dario Goldfarb(2)
    Hiroshi Ito(2)
    C. Grant Willson (6)
    David Patterson (1)
    Rama Puligadda (3)
    C. Devadoss(3)
    Marie Angelopoulos(2)
    Ralph Dammel(5)
    Frank Houlihan (5)
    Karen Turnquest(4)
     
     
     
     
     
     
     
     
     
     
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    Electronics Materials Group
    Polymers Division
    Materials Science and Engineering Laboratory

     
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