Technical Activities 1997

L.E. Smith, Chief
B.M. Fanconi, Deputy

NISTIR 6065
U.S. Department of Commerce
Technology Administration
National Institute of Standards and Technology

Introduction

Technical Activities

Electronic Packaging, Interconnection, and Assembly Program
Overview 1
FY-97 Significant Accomplishments
Improved Measurement Technique for Hydrothermal Expansion of Polymer Thin Films
Thermal Properties Measurement
Industry Coordination and Workshops in Electronic Packaging, Interconnection and Assembly
Ultra-thin Polymer Films
Dielectric Measurements of Thin Films from DC to 1 GHz
Residual Stress in Polymer Films Adhered to Silicon Substrates
Moisture Effects in Electronic Packaging Polymers
Interfacial Energy Between Solids
Aging of Light Emitting Polymers

Polymer Blends and Processing Program
Overview
FY-97 Significant Accomplishments
Phase Behavior and Pair Interaction Parameters in Polymer Blends
Structure Formation by Shear in Polymer Blends
On-Line Morphological Characterization of Polymer Blends
Fluorescence Monitoring of Polymer Processing
Interfacial Interactions in Multi-Phase Systems
Stabilization of Blends by Strong Interactions
Pattern Formation by Polymer Blends in Coatings and Adhesive Layers
Phase Behavior of Polyolefin Blends
Polymer-Filler Interactions
Characterization and Applications of Dendrimer-Polymer Blends
Polymer Solutions
Polymer Blends and Processing Center

Polymer Composites Program
Overview
FY-97 Significant Accomplishments
Liquid Composite Molding: Development of Permeability Measurement Techniques and Data
Liquid Composite Molding: Development and Verification of Process Simulation Models
Liquid Composite Molding: Development and Verification of Permeability Prediction Models
Liquid Composite Molding: Bulk Resin Measurements for Process Monitoring and Control
Liquid Composite Molding: Interphase Sensitive Sensors for Process Monitoring
Microstructure Studies: Performance Relationship
Microstructure Studies: Improve the Utility of the Single Fiber Fragmentation Test
Optical Coherence Tomography of Polymer Composites
Environmental Durability Studies: Development of Processing Methods to Fabricate Urethane Samples

Polymer Characterization Program
Overview
FY-97 Significant Accomplishments
Standard Reference Materials
Mass Spectrometry of Polymers
Characterization of Polymers by Spectroscopic Techniques
Characterization of Polymer Morphology by Microscopy Techniques
Structural Characterization of Polymers by Small Angle X-Ray Scattering
Descriptive Measures for Small-Angle Scattering (SAS)
Nonlinear Viscoelasticity of Solid Polymers
Task 1.
Time-Temperature, Time-Aging Time and Time-Strain Superposition below the Glass Transition
Task 2. Volumetric Behavior for Stress Relaxation Experiments in Tension and Compression of Polycarbonate below the Glass Transition Temperature

Physical Aging and Structural Recovery in Polymers
Task 1.
Isobaric and Isochoric Responses of Polymers
Task 2. Dilatometric Investigation of the Structural Recovery of Polymer Glasses
Task 3. The Physical Aging Response of Industrial Materials
Task 4. Effects of Structural Recovery on Modulated and Dynamic Thermal Measurements
Task 5. Physical Aging and Structural Recovery in Polymeric Glasses in Plasticizing Environments

Failure in Polymers and Adhesives
Task 1
. Finite Element Analysis of Interfacial Crack Propagation Criterion Based on Local Shear (Near Tip Deformation and Fracture)
Task 2. Hygrothermal Aging of Commercial Adhesives
Task 3. Measurement of Craze Initiation and Growth in Polymers

Rheological Characterization of Polymer Dynamics
Task 1.
Develop a Nonlinear Fluid Standard
Task 2. Viscoelastic Constitutive Model for the Creep Behavior of Poly-urethane Foams

Dental and Medical Materials Program
Overview
FY-97 Significant Accomplishments
Dental Resins Based on Fluorinated Monomers and Oligomers
Dental Composites with Improved Interfaces
Improved Adhesive Systems for Bonding to Tooth Structure
Polymer-modified Porous Ceramics: Interpenetrating Phase Composites for Dental Applications
Measurement Methods for Process Control of Cell Encapsulation
Bioactive Polymeric Dental Materials with Remineralization Potential Based on Amorphous Calcium Phosphate
Support for the Biomaterials Integrated Products Industries

Theory and Modeling Program
Overview
FY-97 Significant Accomplishments
Theory and Modeling of Polymer Phase Transitions
Theory and Modeling of the Properties of Polymer Blends, Films and Solutions

Other Projects
Development and Utilization of Test Methods for Qualification of Passport Laminates

Division Management

Research Staff

Certain commercial materials and equipment are identified in this report in order to specify adequately the experimental procedures. In no case does such identification imply recommendation or endorsement by the National Institute of Standards and Technology (NIST) nor does it imply necessarily the best available for the purpose.